| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 203349 | Fluid Phase Equilibria | 2013 | 5 Pages |
The object of this study is to measure the liquid–liquid equilibrium (LLE) data in fluorous solvent (perfluorohexane and Galden® HT-135) mixtures, which are used as environmentally benign reaction solvents. The LLE data of perfluorohexane + n-alkane (C7, C9, and C10) mixtures were measured to determine the phase behavior of perfluorohexane + n-alkane (C6–C10) mixtures. The LLE for Galden HT-135® + dibutyl ether/butyl acetate mixtures were measured up to the upper critical solution temperature (UCST). The experimental results for the LLE were represented using the NRTL activity coefficient model.
► This study investigates measurements of LLE data containing two fluorous solvents. ► Perfluorohexane and Galden® HT-135 were investigated as fluorous solvent. ► LLE data of mixtures perfluorohexane + n-alkane (C7, C9, and C10) were measured. ► LLE data of mixtures Galden HT-135® + dibutyl ether / butyl acetate were also measured. ► Experimental LLE data were represented by NRTL model.
