Article ID Journal Published Year Pages File Type
203431 Fluid Phase Equilibria 2007 5 Pages PDF
Abstract

The empirical correlation developed in a previous paper is extended to hydrogen bonding and quantum pure compounds. The calculations of the second virial coefficients only require additional parameters, the reduced dipole moment for the associated compounds (alcohols, amines, water) and reduced de Broglie wavelength for the quantum compounds (H2, D2, T2, 3He, He, Ne). The results agree well with experimental data.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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