Article ID Journal Published Year Pages File Type
203516 Fluid Phase Equilibria 2009 6 Pages PDF
Abstract

In an equilibrium vessel, the solubility of antioxidant 1010 in pure alkanols was measured in the temperature range from 283.15 K to 343.15 K using a method in which an excess amount of solute was equilibrated with the alkanol solution. The liquid concentrations of the investigated antioxidant 1010 in the saturated solution were analyzed by UV-spectrometry. The solubility data have been correlated as functions of the temperature. Activity coefficients for antioxidant 1010 have been calculated by means of the Wilson, NRTL and UNIQUAC equations and with them were correlated solubility data that were compared with the experimental ones. The best correlation of the solubility data has been obtained by the Wilson equation, by which the average root-mean-square deviation of temperature for the seven systems is 0.62 K.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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