Article ID Journal Published Year Pages File Type
203913 Fluid Phase Equilibria 2006 8 Pages PDF
Abstract

Isobaric vapor–liquid equilibrium (VLE) data are reported at 101.3, 80.0 and 53.3 kPa for six binary systems of 1-chlorobutane with heptane, cyclohexane and toluene, and 2-chlorobutane with the same hydrocarbons. The experimental isobaric T, x and y data were fitted to four two-parameter models namely Redlich–Kister, NRTL (α12 = 1), Wilson and UNIQUAC. The maximum likelihood principle was applied to adjust the model parameters.

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