Article ID Journal Published Year Pages File Type
204495 Fluid Phase Equilibria 2011 4 Pages PDF
Abstract

Solid–liquid equilibria in the C12H22O11–Ca(OH)2–H2O system have been determined at 30 °C. Two phases C12H22O11·3Ca(OH)2 and C12H22O11·2Ca (OH)2 have been evidenced, and solubility (liquidus) curves have been determined. It is thus shown that these ternary phases exhibit incongruent solubilities at 30 °C. These solid phases were characterized using Infrared Spectroscopy (IR), Scanning Electron Microscopy (SEM) and Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES).

► Isothermal 30 °C study of heterogeneous equilibria in C12H22O11–Ca(OH)2–H2O system. ► Solubility (liquidus) curves have been determined. ► Two phases C12H22O11·3Ca(OH)2 and C12H22O11·2Ca (OH)2 have been evidenced. ► This work shows that these ternary phases exhibit incongruent solubilities at 30 °C.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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