Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
205978 | Fuel | 2015 | 9 Pages |
•Carbonate-based ionic liquids can be used to remove naphthenic acids from crude oil.•The reaction mechanism involves the formation of an ionic liquid-naphthenic acid complex.•The complex can be reacted with carbonic acid to reform the ionic liquid.•Recycling of the ionic liquid has been demonstrated.
A number of tetraalkylammonium methylcarbonate and hydrogencarbonate based ionic liquids are shown to be capable of reacting with the naphthenic acids contained in Doba crude oil via a neutralisation reaction. Spectral studies show that the ionic liquids neutralisation mechanism involves the formation of an ionic liquid-naphthenate complex, liberating methanol and carbon dioxide. Extraction of the neutralised complex into a separate methanol phase and subsequent regeneration using aqueous carbonic acid results in ∼70% of the ionic liquid being recovered for recycle. Isolation of the naphthenic acids shows that these make up to 0.85 wt% of the crude oil. Speciation of the naphthenic acids shows a mixture of monocyclic, through to tetracyclic structures with carbon numbers in the range C12–C40.