| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 210530 | Fuel Processing Technology | 2011 | 14 Pages |
Anodic alumina membranes were prepared by anodizing aluminum followed by chemical and hydrothermal treatments. Anodization was performed on both tube surfaces. External anodization was restricted to selected spots leaving an aluminum mechanically strong frame. Nitrogen sorption data analysed with the CPSM method (Corrugated Pore Structure Model) detected a mesopore structure (i.e. Dmean;15–20) and surface areas of 2–20 m2/g. SEM microscopy images revealed a regular pore structure of independent pores with densities of Npore ~ 5.6 × 1014 pores/m2. Single gas permeances (Π) for X: H2, CH4, CO and CO2 were measured on a Wicke–Kallenbach apparatus at varying mean transmembrane pressure Pm by the “dead-end” method. The observed slight dependence of Π on Ρm is indicative of strong Knudsen diffusion and weak viscous flow contributions. By correlating the experimental data with a linear Π vs Ρm relationship, Knudsen contribution evaluation was enabled, and found to vary in the range KC ≈ 0.7–1.0. The Knudsen number criterion for flow regime discrimination is critically discussed and a realistic dual Knudsen number approach is proposed. Experimental permselectivities αΗ2Χ = ΠH2/ΠX (X ≠ H2) approach by 70–100% their Knudsen selectivity counterparts. Anodic alumina membranes exhibit pore structure and gas permeability characteristics useful in designing integrated gas separation and catalytic membrane reactor systems.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► High hydrogen content syngas is important in optimizing fuel cell efficiency. ► Hydrogen permselective porous membranes are a promising gas upgrading technology. ► Anodic alumina membranes (AAM) enabled Knudsen diffusion hydrogen permselectivity. ► Robust tubular AAM were fabricated by applying a spotted outer surface anodization. ► AAM may favor optimized hydrogen selective separation and CO converter operation.
