Recovery of indium from etching waste by solvent extraction and electrolytic refining

A large amount of an etching waste containing indium is wasted by plants manufacturing liquid crystal displays. In this study, the recovery of indium from the etching waste by solvent extraction and electrolytic refining was investigated. Initially, major impurities, such as aluminum and molybdenum, were removed by dissolution using sodium hydroxide. From the resulting etching cake, solvent extraction of indium was studied for the extractant of PC88A. Indium was extracted efficiently in an acidity range of 0.1 to 0.5 mol/dm3 (MH+). PC88A extracts indium, aluminium, molybdenium, and iron from the HCl medium, but indium could be selectively stripped from the loaded solvent. The conditions for continuous running on a pilot scale using PC88A were obtained. The resulting indium solution was further purified to metal by electrolytic refining so that the final purity of the indium metal was 99.997%.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► In this study, we recovered indium from etching waste from plants manufacturing LCD. ► We extracted indium from the etching waste using PC88A as an extractant. ► We obtained a continuous running condition for solvent extraction. ► We metalized the indium solution to obtain a purity of 99.997% by electrolytic refining.