Adsorption of oleate on fluorite surface as revealed by atomic force microscopy

The adsorption of oleic acid / oleate on fluorite surface could be visualized using tapping mode of atomic force microscopy (AFM). The natural fluorite crystals were equilibrated with 10− 3 to 10− 7 M oleate solutions and their AFM images at each concentration along with height profiles were recorded. Even at low oleate concentration of 1 × 10− 7 M, concomitant monolayer and bilayer structures were observed. It suggests that normal–normal bonding of hydrocarbon chains takes place before the surface is completely covered by the monolayer. Multi-layer adsorption of oleate was observed at oleate concentrations of above 10− 4 M. The tapping mode AFM can be utilized to visualize the topography of surfaces adsorbed with surfactant molecules.