Article ID Journal Published Year Pages File Type
214965 The Journal of Chemical Thermodynamics 2016 5 Pages PDF
Abstract

•Vapour pressures of two pure potential dry-cleaning solvent were measured.•Measurements were made over the temperature range of (294.6–442.7) K.•Three commonly used vapour pressure equations were fitted to the experimental data.•The parameters of Antoine and Wagner type equations were estimated.•The relative deviations (rmsd) from the three vapour-pressure equations were <0.6%.

Saturated pressures of 1-(butoxymethoxy)butane (dibutoxymethane) and 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane (methyl nonafluorobutyl ether), new potential solvents for dry-cleaning processes, were measured with a dynamic recirculation apparatus at a pressure range of (15–80) kPa, at temperatures of (390.4–442.7) K for dibutoxymethane and (294.6–322.4) K for methyl nonafluorobutyl ether. The vapour pressures were represented using the correlations of Antoine, extended Antoine and Wagner with relative root mean square deviations of, 1%, 6% and 0.6% for dibutoxymethane, and, 1%, 2% and 0.6% for methyl nonafluorobutyl ether, respectively. The experimental data of dibutoxymethane was compared with those available in literature, the result showed consistency between both data sets.

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