Article ID Journal Published Year Pages File Type
215410 The Journal of Chemical Thermodynamics 2014 5 Pages PDF
Abstract

•VLE of (pyridine + [EMIM][SCN]), or (thiophene + [EMIM][SCN]) binary mixtures were measured.•The investigated temperatures are 273 K to 363 K.•The PC-SAFT equation of state has been used to correlate the vapour pressures of the binary systems.

In this work (vapour + liquid) equilibrium (VLE) measurements were performed on binary systems of the ionic liquid 1-ethyl-3-methylimidazolium thiocynate [EMIM][SCN] with thiophene or pyridine at pressures close to the atmospheric pressure using a static device at temperatures between 273 K and 363 K. Experimental data were correlated by the PC-SAFT EoS. The binary interaction parameters kij were optimised on experimental VLE data. The results obtained for the two binary mixtures studied in this paper indicate that the PC-SAFT EoS can be used to represent systems containing ionic liquids.

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