Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
215588 | The Journal of Chemical Thermodynamics | 2014 | 5 Pages |
•A new set of Henry’s constant for the system carbon dioxide-aqueous deep eutectic solvents were measured.•The DESs used were: ethaline, glyceline, and maline.•The measured data were reported as functions of temperature and composition.•The measured data were represented satisfactorily by the applied correlations.
In this study, we present a new set of Henry’s constant data for the system carbon dioxide-aqueous deep eutectic solvent (DES) (20 to 80 wt% DES) at T = (303.15, 308.15, and 313.15) K. The DESs used were choline chloride-based: ethaline (choline chloride/ethylene glycol), glyceline (choline chloride/glycerol), and maline (choline chloride/malonic acid). A differential Henry’s coefficient model was used to describe the behaviour of Henry’s constant, and correlate it with temperature and concentration of DES in the aqueous DES solution. The correlation was found satisfactory such that the proposed model can be used in engineering calculations with reasonable accuracy.