Article ID Journal Published Year Pages File Type
215704 The Journal of Chemical Thermodynamics 2012 7 Pages PDF
Abstract

(Liquid + liquid) equilibrium (LLE) data for {water (1) + methanol (2) + β-citronellol (3)} and {water (1) + ethanol (2) + β-citronellol (3)} ternary systems at T = (283.15, 298.15, and 313.15) K are reported. The immiscible region of (water + methanol + β-citronellol) system was found to be larger than that for the ethanol system at the same temperature. The effect of the temperature on the ternary (liquid + liquid) equilibria was examined and discussed. The experimental (liquid + liquid) equilibrium data have been satisfactorily represented by using extended UNIQUAC and modified UNIQUAC models.

► Ternary (liquid + liquid) equilibria containing β-citronellol are reported. ► The influence on temperatures on the systems was examined and discussed. ► The immiscible regions between methanol and ethanol systems were compared. ► The experimental data have been satisfactorily represented by using UNIQUAC models.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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