Article ID Journal Published Year Pages File Type
215952 The Journal of Chemical Thermodynamics 2013 6 Pages PDF
Abstract

•Thermophysical properties of liquid Ti are obtained by electrostatic levitation.•How to measure the thermophysical properties is shown with non-contact method.•Hypercooling limit of liquid Ti guarantying homogeneous nucleation is 341 K.•Accurate ratio Cp/εT of the liquid Ti is obtained with weak temperature dependence.•Interfacial free energy of Ti is estimated with the thermophysical parameters.

Thermophysical properties of liquid Ti are measured by a newly developed electrostatic levitation. In this study, we measure a hypercooling limit (ΔThyp), specific heat (Cp), total hemispherical emissivity (εT), and density (ρ) of liquid Ti. The ΔThyp of the liquid Ti is 341 K. The Cp of the liquid Ti shows very weak temperature dependence during supercooling. The εT and ρ of the liquid Ti are given by 0.329 and ρ(T) (g/cm3) = (4.16 − 2.36) · 10−4 (T − Tm). Finally, the interfacial free energy is estimated with the measured thermophysical parameters. The interfacial free energy is 0.164 J/m2, and Turnbull’s coefficient is 0.48.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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