Article ID Journal Published Year Pages File Type
216222 The Journal of Chemical Thermodynamics 2012 5 Pages PDF
Abstract

(Vapour + liquid) equilibrium (VLE) data for the binary system of {trifluoroiodomethane (R13I1) + trans-1, 3, 3, 3-tetrafluoropropene (R1234ze (E))} were measured by a static-analytic method within the temperature range of (258.150 to 298.150) K. The experimental data were correlated using the Peng–Robinson equation of state (PR EoS) with the Huron–Vidal (HV) mixing rule involving the NRTL activity coefficient model. The results show good agreement with experimental values for the binary system at each temperature point. The maximum average absolute relative deviation of pressure is 0.28%, while the maximum average absolute deviation of vapour phase mole fraction is 0.0025. Obviously azeotropic behaviour can be found for the measured temperature range here.

► VLE data for {R13I1 + R1234ze (E)} systems were measured. ► This work was based on the static-analytic method. ► The VLE data were correlated using the PR-HV-NRTL model. ► Obviously azeotropic behavior can be found.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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