Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
216382 | The Journal of Chemical Thermodynamics | 2012 | 9 Pages |
The acid–base properties of four aminophenol derivatives, namely m-aminophenol (L1), 4-amino-2-hydroxytoluene (L2), 2-amino-5-ethylphenol (L3) and 5-amino-4-chloro-o-cresol (L4), are studied by potentiometric and titration calorimetric measurements in NaCl(aq) (0 ⩽ I ⩽ 3 mol · kg−1) at T = 298.15 K. The dependence of the protonation constants on ionic strength is modelled by the Debye–Hückel, SIT (Specific ion Interaction Theory) and Pitzer equations. Therefore, the values of protonation constants at infinite dilution and the relative interaction coefficients are calculated. The dependence of protonation enthalpies on ionic strength is also determined. Distribution (2-methyl-1-propanol/aqueous solution) measurements allowed us to determine the Setschenow coefficients and the activity coefficients of neutral species. Experimental results show that these compounds behave in a very similar way, and common class parameters are reported, in particular for the dependence on ionic strength of both protonation constants and protonation enthalpies.
► Protonation thermodynamics of four aminophenol derivatives were determined. ► Dependence on ionic strength was analysed by using different models. ► Neutral species activity coefficient was determined by distribution measurements. ► Acid–base behaviour of this ligand class was modelled.