Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
216501 | The Journal of Chemical Thermodynamics | 2007 | 6 Pages |
Abstract
The sodium oxide activity established by the equilibrium between Na2ZrO3(s) and ZrO2(s) is subject to a continual change upon varying the composition of the phase mixture. This is revealed from the results of a solid state electrochemical approach that allows sensitive differentiation between univariance and bivariance of the phase equilibrium under consideration, thus indicating the occurrence of a noticeable sodium nonstoichiometry presumably in sodium zirconate.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
H. Näfe, R. Subasri,