Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
216703 | The Journal of Chemical Thermodynamics | 2010 | 7 Pages |
Abstract
Densities and speeds of sound at atmospheric pressure and temperatures of (283.15, 298.15, and 313.15) K for the binary mixtures formed by n-hexane or n-heptane with isomeric chlorobutanes were determined. Afterwards excess volumes, excess isentropic compressibilities and excess speeds of sound were calculated using the experimental data and correlated using a Redlich–Kister type equation. Finally, the results were studied using the Prigogine–Flory–Patterson theory showing excellent predictions for speed of sound and isentropic compressibility values of mixtures as well as a strong influence of the interactional contribution term for excess volume values.
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Physical Sciences and Engineering
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Authors
H. Guerrero, G. Pera, I. Giner, I. Bandrés, C. Lafuente,