Article ID Journal Published Year Pages File Type
216844 The Journal of Chemical Thermodynamics 2010 4 Pages PDF
Abstract

The molar heat capacities of the (water + acetonitrile) mixtures have been measured at T = (283.15, 298.15, 313.15, and 328.15) K as a function of mole fraction. The excess molar heat capacities, CpE, limiting partial molar heat capacities of water and acetonitrile C¯p∘ have been calculated. The excess molar heat capacities are positive over the whole mole fraction range and increase with increasing temperatures from (283.15 to 328.15) K. The excess molar heat capacities have been fitted to the Redlich–Kister equation.

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