Article ID Journal Published Year Pages File Type
217016 The Journal of Chemical Thermodynamics 2008 8 Pages PDF
Abstract

Densities, ρ, and viscosities, η, of binary mixtures (N-methylmorpholine + benzene, + toluene, and + cyclohexane) were measured over the whole mole fraction range at T = (298.15, 303.15, 313.15, 323.15) K. Densities and viscosities were used to compute the excess molar volumes VE, viscosity deviation Δη  , and the excess free energies of activation for viscous flow ΔG∗EΔG∗E. These data have been fitted to Redlich–Kister polynomial equation to derive the coefficients and estimate the standard deviation values. A discussion on these quantities in terms of molecular interactions is reported.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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