| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 217017 | The Journal of Chemical Thermodynamics | 2008 | 8 Pages |
Abstract
The heat capacity measurements of the crystalline phosphate CsMgPO4 of a tridymite structure were performed between T = (7 and 650) K. The thermodynamic functions Cp,m∘/R, Δ0THm∘/RT, Δ0TSm∘/R, and Φm∘/R were calculated and the fractal dimension Dfr evaluated. From the solution reaction calorimetry, the standard enthalpy of CsMgPO4 formation at T = 298.15 K was found. Thermochemical parameters of formation ΔfGm∘ and lgKf,m∘ were determined by combining the data obtained by these techniques.
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Chemical Engineering
Chemical Engineering (General)
Authors
E.A. Asabina, A.R. Zaripov, V.I. Pet’kov, A.V. Markin, K.V. Kir’yanov, N.N. Smirnova, S.I. Rovny,