Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
217244 | The Journal of Chemical Thermodynamics | 2007 | 6 Pages |
Abstract
Viscosities at T = (293.15, 298.15, and 303.15) K in the binary mixtures of ethyl tert-butyl ether with 2-ethoxyethanol, 2-(2-ethoxyethoxy)ethanol, and 2-[2-(2-ethoxyethoxy)ethoxy]ethanol have been measured over the entire range of mixture compositions. From the experimental data, deviations in the viscosity (Δln η) and excess energies of activation for viscous flow (ΔG∗E) have been calculated. The viscosity data were correlated with equations of Hind et al., Grunberg and Nissan, Auslaender, and McAllister. The results for Δln η and ΔG∗E are discussed in terms of intermolecular interactions and structure of studied binary mixtures.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Aneta Ćwiklińska, Tomasz Dzikowski, Dariusz Szychowski, Wojciech J. Kinart, Cezary M. Kinart,