Article ID Journal Published Year Pages File Type
217270 The Journal of Chemical Thermodynamics 2008 5 Pages PDF
Abstract

The effect of temperature on the (liquid + liquid) equilibrium of the aqueous solution of surfactant polyoxyethylene cetylether (with abbreviation name Brij 58) and diammonium hydrogen phosphate has been investigated at T = (303.15, 313.15, 323.15, and 333.15) K. The Flory–Huggins equation with two electrostatic terms (Debye–Huckle and Pitzer–Debye–Huckle equations) was used to correlate the phase behavior of this system. Good agreement has been found between experimental and calculated data from both models. The results indicated that the enlargement of the two-phase region upon increasing the temperature. Additionally temperature dependency of the parameters of the Flory–Huggins model has been calculated.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , , ,