Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
219827 | Journal of Electroanalytical Chemistry | 2010 | 7 Pages |
Abstract
The voltammetric response of a bipolar cell, formed by making electrical connection between two half-cells under overall potentiostatic control, is described. Experimental data obtained with reversible redox couples are compared with numerical simulations of the corresponding two-phase transport problem, where charge transfer may be limited by the transport of either, or both, of the redox-active couples. Preliminary experiments on the extension of the system to more complex electron transfer processes, specifically metal deposition, are also described.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Daniela Plana, Fran G.E. Jones, Robert A.W. Dryfe,