Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
220246 | Journal of Electroanalytical Chemistry | 2009 | 5 Pages |
The electrocatalytic oxidation of formaldehyde on palladium nanoparticles electrodeposited on carbon ionic liquid electrode (Pd–CILE) has been investigated. The ionic liquid, octylpyridinum hexafluorophosphate ([C8Py+]PF6-) was incorporated in the electrode as the binder. The general electrochemical behavior was characterized by cyclic voltammetry in alkaline media. The results show that the Pd–CILE system exhibits a significant electrocatalytic activity towards oxidation of formaldehyde. An oxidation peak was obtained at a potential of ∼0.03 V vs. Ag/AgCl for 0.010 M formaldehyde. The interesting feature of this electrode is that its catalytic efficiency as well as its anti poisoning property are far superior compared to many of the previously reported formaldehyde sensors.