Article ID Journal Published Year Pages File Type
221057 Journal of Electroanalytical Chemistry 2007 6 Pages PDF
Abstract

The electrochemical oxidation of N-thioamidohydrazone, 1, was undertaken at platinum electrode in acetonitrile containing lithium perchlorate as supporting electrolyte and monitored via cyclic voltammetry and controlled potential coulometry. An overall process consisting of an irreversible two electron transfer involving, in absence or presence of a base, deprotonation and intramolecular cyclization reactions enables the formation of 1,2,4-triazol-3-thione in a satisfactory yield.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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