Article ID Journal Published Year Pages File Type
221211 Journal of Electroanalytical Chemistry 2006 10 Pages PDF
Abstract

Analytical approximations for steady-state positive feedback currents in scanning electrochemical microscopy (SECM) experiments using a microdisk are discussed. The use of a conformal map transformation leads to the use of new mathematical functions. A general analytical expression for all values of tip–substrate distances and all types of microdisk (with various insulator thicknesses) are thus obtained with only four adjustable parameters.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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