Article ID Journal Published Year Pages File Type
221421 Journal of Electroanalytical Chemistry 2006 8 Pages PDF
Abstract

The oxidation of ammonia has been studied using Differential Electrochemical Mass Spectrometry on the three Pt basal planes. The observed products N2, NO and N2O were obtained for the three platinum single crystals. The sensitivity of the ammonia oxidation towards Pt(1 0 0) sites is highlighted as well as the presence of a poison formed during the oxidation that blocks the surface. This species seems to inhibit the N2 formation at lower potentials than for NO and N2O.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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