Article ID Journal Published Year Pages File Type
222442 Journal of Environmental Chemical Engineering 2015 5 Pages PDF
Abstract

•A strong solid base catalyst was prepared from waste eggshell.•The generated potassium hydroxide enhances its basicity and catalytic ability.•The solid base exhibits excellent catalytic activity and stability in the reaction.

A strong solid base catalyst was prepared from waste eggshell by KF modification and thermal treatment. The eggshell catalyst was characterized by Fourier-transform infrared spectra (FT-IR), X-ray diffraction (XRD), scanning electron microscope (SEM) and solid-state nuclear magnetic resonance (NMR) spectroscopy. The characterization results show that potassium hydroxide (KOH) formed from the modification process enhances the basicity and catalytic ability of the catalyst. The solid base catalyst from eggshell (SBES) exhibits excellent catalytic activity and stability in the transesterification reaction, which suggested that this catalyst would be potentially used as a solid base catalyst for biodiesel production.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideA strong solid base catalyst was prepared from waste eggshell by KF modification and thermal treatment. The characterization results show that KOH generated in the modification process enhances the basicity and catalytic ability of the catalyst. The solid base catalyst from eggshell exhibits excellent catalytic activity and stability in the transesterification reaction, which suggested that this catalyst would be potentially used as a solid base catalyst for biodiesel production.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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