Article ID Journal Published Year Pages File Type
227547 Journal of Industrial and Engineering Chemistry 2014 5 Pages PDF
Abstract

•TTIP readily decomposes at a much lower temperature in the presence of hydrogen.•Ti was selectively deposited on Pd active sites over a SiO2 support under a hydrogen atmosphere.•Pd surface is effectively modified by the selectively deposited Ti species.•Pd–Ti/SiO2 showed high ethylene selectivity than unmodified Pd/SiO2 in acetylene hydrogenation.

In this paper, we describe a novel method for selectively attaching TiO2 promoters on Pd surfaces in Pd/SiO2 catalysts using selective chemical vapor deposition (CVD). Ti was selectively deposited on Pd active sites over a SiO2 support under a hydrogen atmosphere when titanium tetraisopropoxide was used as a Ti precursor. The Pd–Ti/SiO2 catalyst modified by CVD exhibits approximately 1.8 times higher ethylene selectivity than the un-modified Pd/SiO2 catalyst in the selective hydrogenation of acetylene due to the effective geometric modification of the Pd surface, which is beneficial to ethylene selectivity, by the selectively deposited Ti species.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , , ,