Article ID Journal Published Year Pages File Type
230986 The Journal of Supercritical Fluids 2012 19 Pages PDF
Abstract

Vapor–liquid critical locus (x, Tc, Pc) has been determined, in the whole range of mole fractions, for the systems {n-hexane + methanol, or +ethanol, or +propan-1-ol, or +butan-1-ol} and {CO2 + methanol, or +ethanol, or +propan-1-ol, or +butan-1-ol}.A comprehensive bibliographic review for the vapor–liquid equilibrium (VLE) and the critical locus of these systems has been performed, and they have been modelled with PC-SAFT EoS. The three parameters that characterize the segments of pure compounds have been rescaled from their critical point values. In all cases, the classical mixing rules and temperature-dependent binary interaction parameters kij(T)=kij0+kij1T have been used.The average deviations obtained for the n-hexane + alkan-1-ol binary mixtures are: for critical loci, mean relative deviation in critical temperature MRD(Tc) = 0.47% and in critical pressure MRD(Pc) = 3.38%; for VLE, mean relative deviation in bubble pressure MRD(P) = 2.90% and absolute deviation for the solvent mole fraction in the vapor phase ΔyC6H14=0.031.The average deviations obtained for the CO2 + alkan-1-ol binary mixtures are MRD(Tc) = 1.91% and MRD(Pc) = 5.93%; MRD(P) = 7.07% and ΔyCO2=0.022.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Vapor–liquid critical locus has been determined for {n-C6H14 or CO2 + alkan-1-ol} mixtures. ► A comprehensive bibliographic review for the VLE and critical locus of these systems has been performed. ► These systems have been modeled with PC-SAFT EoS.

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