| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 231784 | The Journal of Supercritical Fluids | 2008 | 4 Pages |
Abstract
Series of chiral monodentate phosphite-type ligands has been evaluated in the rhodium-catalyzed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2. High reactivities (100% conversion in 1.5–3 h) and enantioselectivities (up to 90%) were obtained in the hydrogenation in scCO2.
Graphical abstractSeries of chiral monodentate phosphite-type ligand have been evaluated in the rhodium-catalyzed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2. High reactivities (100% conversion in 1.5–3 h) and enantioselectivities (up to 90 %) were obtained in the hydrogenation in scCO2.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
S.E. Lyubimov, E.E. Said-Galiev, A.R. Khokhlov, N.M. Loim, L.N. Popova, P.V. Petrovskii, V.A. Davankov,