Examination of NaCl and MIBC as bubble coalescence inhibitor in relation to froth flotation

With scarcity of fresh water resources, flotation plants are increasingly under pressure to supply their water needs from other sources such as bore water, seawater or recycled plant water. This water generally contains a high concentration of inorganic electrolytes which may have a substantial influence on the performance of the flotation operation. In this study, the stabilisation mechanism of bubbles by salt was investigated using a specifically designed experimental set-up. Two bubbles of approximately the same size were produced at the tip of two adjacent capillaries in concentrated solutions of an inorganic electrolyte (NaCl). Their coalescence behaviour was recorded using high speed video imaging in which information such as coalescence time and deformation of the resultant bubble upon coalescence could be extracted. The results were then compared against a similar system using MIBC. It was found that delayed coalescence in NaCl required a relatively concentrated solution in the order of 0.1–0.5 M to achieve coalescence times comparable to MIBC. Unlike NaCl, it appears that a small amount of MIBC, in the order of 10−5 M, is sufficient to delay the coalescence of bubbles, which reach a maximum at a concentration of 3 × 10−3 M. The analysis of oscillation patterns during the coalescence process revealed that the oscillation is noticeably damped in the presence of MIBC at high concentrations, although this is not the case in NaCl solutions. Results are discussed in terms of bubble stability, froth stability and their possible implications on particle recovery.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Coalescence of bubble pairs in solutions of electrolyte (NaCl) and surfactant (MIBC) were studied. ► The coalescence time increases significantly only beyond molar concentrations in NaCl. ► Gibbs elasticity is suppressed at high MIBC concentrations. ► No change in bubble deformation upon coalescence was observed under practical flotation condition.