Article ID Journal Published Year Pages File Type
237092 Powder Technology 2012 5 Pages PDF
Abstract

Magnesium phosphide (Mg3P2) microstructures having microwire shapes with ultrahigh-aspect-ratio and three-dimensional (3D) urchin, flower, and branched shapes (myriapod or leaf) are synthesized using a one-step reaction without any catalysts or templates. The microstructures with different shapes are easily controlled through various temperatures. With increasing reaction temperature, the morphology of Mg3P2 microstructures changes from microwires with ultrahigh-aspect-ratio to branched shapes similar to myriapods or leaves. The growth mechanisms of these microstructures are discussed in detail.

Graphical abstractMagnesium phosphide microstructures having microwire shapes with ultrahigh-aspect-ratio and three-dimensional (3D) urchin, flower, and branched shapes (myriopod or leaf) are synthesized using a one-step gas–solid reaction method without any catalysts or templates.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The novel Mg3P2 microstructure has been prepared successfully by a simple method. ► The microwires with tunable shapes have also been prepared. ► The growth mechanisms of these microstructures are also surveyed.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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