De-agglomeration of hydrophobic and hydrophilic silica nano-powders in a high shear mixer

The effect of energy density, pH and solid concentration on kinetics of de-agglomeration of hydrophobic silica nano-powder in a high shear mixer and on the rheology of resulting suspensions was investigated and compared with de-agglomeration kinetics and rheology of the suspension of hydrophilic silica nano-powder. In both types of nano-powders large aggregates were broken by fracture and erosion. In hydrophobic nano-powder erosion was more pronounced whilst in hydrophilic nano-powder erosion followed initial fracture of large aggregates. At sufficiently high energy input both hydrophobic and hydrophilic aggregates were broken into nano-aggregates but, even at the highest energy input, those nano-aggregates could not have been broken into single nano-particles. Rheology of the suspensions of hydrophobic nano-aggregates strongly depends on pH and on solid concentration whilst rheology of suspensions of hydrophilic nano-powder is rather weakly dependent on those parameters.

Graphical abstractDe-agglomeration of hydrophobic (R816) and hydrophilic (200 V) silica nano-powders (R816) and rheology of resulting suspensions are compared. De-agglomeration of hydrophobic nano-powder requires less energy and in both cases nano-aggregates could not be broken into single nano-particles. Rheology of suspensions of hydrophobic nano-aggregates very strongly depends on pH and on solid concentration.Figure optionsDownload full-size imageDownload as PowerPoint slide