Rheological behavior of carbon nanotube-alumina nanoparticle dispersion systems

In this work, Al2O3 nanoparticle and CNT–Al2O3 nanoparticle suspensions were studied. Both Al2O3 nanoparticle and CNT–Al2O3 nanoparticle systems exhibit shear-thinning behavior. The viscosities increase monotonically with the suspension solids loading. For the 40 vol.% solids loading suspension, CNT effect on the viscosity is not substantial until the content is ≥ 1.3 vol.%. The suspension yield stress to flow provides a measure of the particle–particle networking in the suspension. With the adsorbed poly(acrylic acid) (PAA) layer on the particle surface, substantial colloidal interactions are observed when the solids loading is > 35 vol.% and the CNT content is > 1.3 vol.%. Storage modulus and loss modulus can be used to understand the relative magnitude of the viscoplastic behavior and the elastic behavior of the suspension as well as the transition between the two. The relative magnitude of the dynamic modulii is a strong function of the solids loading and the CNT content.

Graphical abstractBoth Al2O3 nanoparticle and CNT–Al2O3 nanoparticle systems exhibit shear-thinning behavior. The viscosities increase monotonically with the suspension solids loading. CNT effect on the viscosity is not substantial until the content is ≥ 1.3 vol.%. Viscosity and yield stress are proportional to solids loading and CNT content. Storage and loss modulii can be compared to understand suspension rheological behaviors.Figure optionsDownload full-size imageDownload as PowerPoint slide