Second-law analyses applied to internal combustion engines operation

This paper surveys the publications available in the literature concerning the application of the second-law of thermodynamics to internal combustion engines. The availability (exergy) balance equations of the engine cylinder and subsystems are reviewed in detail providing also relations concerning the definition of state properties, chemical availability, flow and fuel availability, and dead state. Special attention is given to identification and quantification of second-law efficiencies and the irreversibilities of various processes and subsystems. The latter being particularly important since they are not identified in traditional first-law analysis. In identifying these processes and subsystems, the main differences between second- and first-law analyses are also highlighted. A detailed reference is made to the findings of various researchers in the field over the last 40 years concerning all types of internal combustion engines, i.e. spark ignition, compression ignition (direct or indirect injection), turbocharged or naturally aspirated, during steady-state and transient operation. All of the subsystems (compressor, aftercooler, inlet manifold, cylinder, exhaust manifold, turbine), are also covered. Explicit comparative diagrams, as well as tabulation of typical energy and exergy balances, are presented. The survey extends to the various parametric studies conducted, including among other aspects the very interesting cases of low heat rejection engines, the use of alternative fuels and transient operation. Thus, the main differences between the results of second- and first-law analyses are highlighted and discussed.