How sulfates and increased temperature affect delayed ettringite formation (DEF) in white cement mortars

In this study,white cement CEM I and white limestone cement CEM II-LL A and Β with 15%, 25% and 35% limestone substitution were studied. The way delayed ettringite is forming due to exposure to increased temperature (50 °C) and external sulfate attack was examined in mortar samples which were immersed for 90 days in three different solutions: (a) saturated solution Ca(OH)2 at 50 °C, (b) saturated solution of Ca(OH)2 at 20 °C and (c) 5% w/w Na2SO4 solution at 50 °C. During this period mortar samples were visually observed regularly while their expansion was estimated on a weekly basis by measuring the change of length with a micrometer. At the end of the 90-days period the compressive strength of the mortars was determined and the deterioration products were identified through means of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and thermogravimetric analysis (DTG). The results of this study show that DEF occurred in two forms. Samples cured at increased temperature contained DEF type I, which caused mediocre expansion and damage. Samples cured at increased temperature in the presence of sulfates produced DEF type II, which caused significant damage on the surface and exhibited high expansion.

► Study of the increased temperature’s effect on expansion of white cement mortars with limestone. ► Study of the sulfate presence’s effect on expansion of white cement mortars with limestone. ► Identificatin of the DEF’s dual nature and why type I or II ettringite was formed. ► Connection of type I/II ettringite to types of deterioration and DEF formation. ► The use of limestone allows for the further study of the durability.