Micromechanical modeling of packing and size effects in particulate composites

This paper is devoted to the introduction of packing and size effects in micromechanical predictions of the overall elastic moduli of particulate composite materials. Whereas micromechanical models derived from the classical ‘point approach’ are known to be unable to model such effects, it is shown that the so-called ‘morphologically representative pattern-based approach’ (MRP-based approach) offers new means of taking some geometrical parameters into account such as the mean distance between nearest-neighbor particles or their size, so as to predict the dependence of the overall moduli on these parameters, at least in a relative way. Moreover, when internal lengths, such as the thickness of interphase shells of coated particles, are introduced, absolute size effects can be predicted as well. Illustrative applications are reported in view of comparisons between such new treatments and the predictions of some classical models which are shown to coincide with the ones derived from MRP-based models in definite limiting cases only.