Article ID Journal Published Year Pages File Type
39674 Applied Catalysis A: General 2014 5 Pages PDF
Abstract

•Preparation of size controlled Ni nanocluster catalyst on alumina without formation of NiAl2O4.•Population of distorted particles increased with decrease in average particle size.•Volcano-shaped size dependence was observed for the activity of water gas shift reaction.

X-ray absorption fine structure (XAFS) and high angle annular dark field scanning transmission electron microscopy (HAADF STEM) were both applied to a characterization of the size regulated Ni nanocluster catalyst on alumina. XAFS analysis showed that NiAl2O4 was not formed in our colloid derived catalyst. The wide variety of coordination number (CN) for Ni–Ni indicated the achievement of the size regulated Ni nanocluster catalyst preparation. HAADF STEM analysis showed narrow size distribution of Ni nanocluster catalyst even after H2 reduction at 673 K. Distorted particles were observed and the ratio of distorted particles increased with decrease in the cluster size. Water gas shift reaction was carried out to investigate the catalysis. Volcano-shaped size dependence was observed for the activity of supported Ni nanocluster catalyst.

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Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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