| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 40297 | Applied Catalysis A: General | 2013 | 7 Pages |
•SO3H-SBA-15 has been successfully used in the synthesis of alkyl levulinates.•Moderate acid strength and hydrophobicity is the key of the catalytic performance.•Alkyl levulinates yield close to 100% is achieved adjusting reaction conditions.
Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel. Catalyst screening indicated that propylsulfonic acid-modified SBA-15 material was the most active one, among tested materials, due to a combination of moderately strong sulfonic acid sites with relative high surface hydrophobicity. Under optimized reaction conditions (T = 117 °C, ethanol/levulinic acid molar ratio = 4.86/1 and catalyst/levulinic acid = 7 wt%) almost 100% of levulinic acid conversion was achieved after 2 h of reaction, being negligible the presence of levulinic acid by-products or ethers coming from intermolecular dehydration of alcohols. The catalyst has been reused, without any regeneration treatment, up to three times keeping almost the high initial activity. Interestingly, a close catalytic performance to that achieved using ethanol has been obtained with bulkier alcohols.
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