Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
40648 | Applied Catalysis A: General | 2012 | 8 Pages |
Catalytic reforming of CH4 with CO2 was investigated on mono and bimetallic Pd(or Pt)-Ni based samples supported on Al2O3 and ZrO2. A simple temperature-programmed procedure was used to study both reforming and coke formation via CH4 or CO decomposition. Catalysts supported on zirconia are more active than alumina-supported samples. The addition of Pt or Pd to Ni/ZrO2, preferably by co-impregnation, prevents coke formation. The co-impregnated Ni-Pd/ZrO2 catalyst looks the most promising for a possible industrial application.
Graphical abstract.Figure optionsDownload full-size imageDownload high-quality image (115 K)Download as PowerPoint slideHighlights► A simple temperature-programmed procedure was used. ► Both CH4/CO2 reforming and coke formation via CH4 or CO decomposition were studied. ► Bimetallic Pd(or Pt)-Ni catalysts on zirconia and alumina were investigated. ► The co-impregnated Ni-Pd/ZrO2 catalyst looks the most promising for an industrial application.