| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 40731 | Applied Catalysis A: General | 2012 | 6 Pages |
A heteropolyanion-based cross-linked ionic copolymer was prepared by the anion-exchange of a newly task-specific designed amino-containing ionic copolymer with a Keggin heteropolyacid, and characterized by FT-IR, SEM, TG, XRD, UV–vis, ESR, 1H NMR, and elemental analysis. Its catalytic activity was evaluated in the epoxidation of alkenes with aqueous H2O2. The resultant heteropolyanion-based ionic copolymer is revealed to be a highly efficient heterogeneous catalyst for epoxidation of alkenes with H2O2, adding the advantages of convenient recovery and steady reuse.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (177 K)Download as PowerPoint slideHighlights► A new heteropolyanion-based amino-containing cross-linked polymeric hybrid is prepared. ► The hybrid catalyst leads to the heterogeneous epoxidation of alkenes with H2O2. ► The hybrid catalyst gives high conversion and selectivity. ► The catalyst shows easy recovery, and very steady reuse.
