Article ID Journal Published Year Pages File Type
40829 Applied Catalysis A: General 2012 7 Pages PDF
Abstract

A F-doped V2O5–WO3/TiO2 has been developed for low-temperature selective catalytic reduction (SCR) of NO with NH3. The aim of this novel design was to improve the activity of a catalyst with low WO3 loading. Analysis by PL spectra, XRD, XPS and EPR showed that F doping improved the interaction of WO3 with TiO2 by oxygen vacancies to facilitate the formation of W5+ that was important to improve the formation of superoxide ions. The experimental results showed that NO conversion could be improved by F doping and V1W3TiF1.35 showed the highest NO removal efficiency in SCR reaction at low temperatures.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (164 K)Download as PowerPoint slideHighlights► The catalytic activity of VWTi was promoted by F doping. ► Improve the interaction of WO3 with TiO2 by F doping. ► Improve the activity of a catalyst with low WO3 loading. ► Investigating the reduced W6+ could improve the NO conversion.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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