| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 41046 | Applied Catalysis A: General | 2012 | 6 Pages |
Although solid niobium has a high surface area, its high Lewis and Brønsted acidity is a drawback that always compromises its catalytic performance in oxidation reactions. In this work, treating the niobium catalyst with hydrogen peroxide circumvents this disadvantage and results in a significant increase in the selectivity of the oxidation of β-pinene. In addition, the efficiency of the niobium catalysts supported on MCM was investigated. Nb-MCM//H2O2 and Nb-MCM were the most active catalysts. Good selectivity of up to 85% at a 93–97% substrate conversion has been achieved. The catalyst can easily be recovered and reused several times without loss in activity.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (85 K)Download as PowerPoint slideHighlights► It was produced a modified niobia with high catalytic capacity for β-pinene oxidation using hydrogen peroxide. ► β-pinene was efficiently converted into the allylic oxidation products in all reactions. ► The Nb-MCM catalyst can easily be recovered and reused several times.
