Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
41197 | Applied Catalysis A: General | 2011 | 7 Pages |
Pd(0) nanoparticles stabilized by polyvinylpyrrolidone (Pd-PVP) with a diameter of 3–6 nm in ethanol catalyzed Heck coupling of iodobenzene with different alkenes under microwave heating. Products were obtained in good yields (62–99%) and good selectivity to the E-isomers. Microwave heating proved to be superior to conventional heating, providing products in higher yields and selectivities in short times (12 min).
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (100 K)Download as PowerPoint slideHighlights► Application of Pd(0)-PVP nanoparticles in Heck coupling reactions. ► Good conversions in short reaction time under MW or conventional heating. ► High turnover frequencies under MW with low loading of Pd(0)-PVP.