Article ID Journal Published Year Pages File Type
41204 Applied Catalysis A: General 2011 12 Pages PDF
Abstract

The [MoVIO2Cl2(thf)2] and [MoIII2(CO)3(MeCN)2] precursor complexes, were immobilized in a hybrid periodic mesoporous organosilicas (PMO)-type material. These new hybrid matrix materials were prepared in one pot synthesis, containing the bidentate N,N′-ligand (glypy) in the material. In a second approach, the ordered mesoporous silica MCM-glypy was prepared using a tethered approach by a stepwise procedure. The metal complexes were grafted in both types of materials to obtain heterogeneous pre-catalysts. The modified materials have been characterized by powder X-ray diffraction, N2 adsorption, and solid-state CP MAS NMR (13C, 29Si).All metal containing materials were tested as catalysts in epoxidation of 1-octene, cyclooctene and styrene with tert-butylhydroperoxide (TBHP) at 328 K. Selectivity to octene and cyclooctene epoxides was complete. The new PMO materials described in this work are outstanding catalysts for any of the transformations described. In fact, cyclooctene selectivity based on TBHP consumption is found to be almost independent of the mol ratio attesting the efficiency of the catalysts. They are also effective under stoichiometric olefin/oxidant ratio. In addition, a mechanism for acid catalyzed benzaldehyde formation is proposed as well as the conversion of Mo(II) to Mo(VI) under catalysis.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (125 K)Download as PowerPoint slideHighlights► Mo complexes with two oxidation states suitable for epoxidation. ► Periodic mesoporous organosilicas (PMOs) were excellent epoxidation catalysts. ► Completely selective systems to octene and cyclooctene epoxides. ► PMOs and MCM-41 based catalysts are more active than homogeneous counterparts. ► Catalysts are effective under stoichiometric olefin/oxidant ratio.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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