| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 41546 | Applied Catalysis A: General | 2010 | 10 Pages |
Etherification of glycerol by isobutylene was conducted in a batch mode using acidic and partially neutralized Amberlyst-15 ionic resin, p-toluenesulfonic acid, silicotungstic acid, cesium salt of silicotungstic acid, and ionic liquid containing sulfonic acid groups. All the catalysts are comparable in terms of the initial rate of glycerol conversion into mono-ether (except cesium salt of heteropolyacid), but differ substantially with respect to the yields of higher ethers of glycerol.Ionic liquid and heteropolyacid are immiscible/insoluble in higher ethers of glycerol. As a result they have unique capability of suppressing the formation of tri-ether during the initial stage of glycerol conversion.Acidic Amberlyst-15 in the form of fine powder has the highest activity per unit weight for glycerol etherification and relatively high activity in isobutene oligomerization. Partial exchange of acidic protons with cations Na+, Ag+, Mg2+, and Al3+ decreases the rates of all the processes, but isobutylene oligomerization is suppressed more efficiently. Ag+- and Al3+-modified Amberlyst demonstrates higher yields of tri-ether and has specific pattern of interaction with gaseous isobutene distinctive to other metal-substituted Amberlysts.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (86 K)Download as PowerPoint slideResearch highlights▶ Glycerol etherification is characterized by slow equilibration of higher ethers. ▶ Product distribution does not follow simplified kinetic model. ▶ Ionic liquid with Brønsted acid sites and heteropolyacid suppress tri-ether formation. ▶ Partial neutralization of Amberlyst 15 suppresses isobutene oligomerization.
