Al-MCM-41 as methanol dehydration catalyst

Al-MCM-41, [SiO2]/[Al2O3] = 30, mesoporous catalysts were synthesized using tetraethylorthosilicate (TEOS) as a source of silica and hexadecyltrimethylammonium bromide (CTAB) as a structure-directing agent (SDA) in the presence of tetrapropylammonium hydroxide (TPAOH) as a co-surfactant additive. The catalytic activities of the calcined samples were evaluated for the dehydration of methanol to dimethyl ether (DME) at 250–450 °C and a gas hourly space velocity (GHSV) of 14,000–80,000 mL g−1cat h−1. Al-MCM-41 samples synthesized in the presence of TPAOH showed higher activity than those synthesized in its absence. The improvement in catalytic activity correlates with the increase in acidity brought about by the enhanced condensation of aluminosilicate framework in the Al-MCM-41 structure. Al-MCM-41 catalysts were also combined with methanol synthesis catalysts to form bifunctional catalysts for the synthesis DME from CO2/H2 at temperature, 260 °C; pressure, 735 psi; GHSV, 2000 mL g−1cat h−1 in a fixed-bed reactor.

Graphical abstractAl-MCM-41, [SiO2]/[Al2O3] = 30, mesoporous catalysts were synthesized in the presence of tetrapropylammonium hydroxide (TPAOH) as a co-surfactant additive. The samples synthesized in the presence of TPAOH showed higher activity than those synthesized in its absence. Al-MCM-41 catalysts were also combined with methanol synthesis catalysts to form bifunctional catalysts for the synthesis of DME from CO2/H2.Figure optionsDownload full-size imageDownload high-quality image (99 K)Download as PowerPoint slide