Pd-promoted WOx/ZrO2 catalysts: Characterization and catalytic activity for n-butane isomerization

The need for environmental friendly catalysts for alkane isomerization has prompted research on the WOx/ZrO2 system. Suitable promoters may improve its activity and stability. We investigated the effect of palladium on WOx/ZrO2 redox properties and catalytic activity for n-butane isomerization. Pd favoured the reduction of WxOy clusters already at RT (redox cycles O2/H2) and in reduced samples EPR identified W5+ surface species.Increasing Pd dispersion increased the catalytic activity. Leached and pre-reduced catalysts resulted to have the highest activity, suggesting that the most active species are WxOy clusters anchored to zirconia surface and interacting with near Pd hydride. For n-butane isomerization Pd-promotion is as effective as Pt-promotion.

Graphical abstractWe investigated the palladium effect on WOx/ZrO2 redox properties and catalytic activity for n-butane isomerization. Pd favoured the reduction of WxOy already at RT and in reduced samples EPR identified three W5+ surface species. Leached and pre-reduced catalysts showed the highest activity, suggesting that the most active species are WxOy clusters anchored to zirconia surface and interacting with near Pd hydride.Figure optionsDownload full-size imageDownload as PowerPoint slide